Chemical Reactions of Amines

IMPORTANT

Chemical Reactions of Amines: Overview

This topic covers concepts such as Alkylation of Amines, Acylation of Amines, Carbylamine Reaction, Reaction of Amines with Nitrous Acid, Reaction of Amines with Benzene Sulphonyl Chlorides, Friedel-Crafts Reactions of Aromatic Amines, etc.

Important Questions on Chemical Reactions of Amines

MEDIUM
IMPORTANT

Identify A, B, C and D in the following process :

(i)   C H 3 C H 2 Cl NaCN A Ni / H 2 reduction B

(ii)   C 6 H 5 N H 2   NaN O 2 / HCl C C 6 H 5 N H 2 / O H D

EASY
IMPORTANT

The products of the following chemical reactions are,

    i C2H5NH2+C6H5SO2Cl

   ii C2H5NH2+HNO2

MEDIUM
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The products of the following chemical reactions are

(i)  C2H5NH2+C6H5SO2Cl

(ii)  C2H5NH2+HNO2H2O

EASY
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Which of the following chemical test can distinguish between methylamine and dimethylamine?

EASY
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Which of the following chemical test can distinguish between methylamine and dimethylamine?

MEDIUM
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The following pairs of computes can be distinguished by which of the following tests:

 (i) Ethylamine and aniline

(ii) Aniline and N-methylaniline

HARD
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The following pairs of compounds can be distinguished by which of the following tests:

(i) Ethyl amine and aniline

(ii) Aniline and N-methyl aniline

EASY
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The test that is done for the differentiation of primary amines from secondary and tertiary amine is:

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In the chemical reaction:
CH 3 CH 2 NH2+ CHCl 3 + 3 KOH A + B + 3 H 2 O , the compound (A) and (B) are respectively:

MEDIUM
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In the following chemical reactions, the compounds A and B are respectively:

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HARD
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In the following reaction sequence,

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the major products X and Z are

MEDIUM
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An organic amino compound reacts with aqueous nitrous acid at low temperature to produce an oily nitrosoamine. The compound is:

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In the following chemical reactions, the compounds A and B are respectively:

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EASY
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Which of the following compounds will form significant amount of meta product during mono-nitration reaction?

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Which of the following compound gives N-nitrosoamine on reaction with nitrous acid?

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The test to distinguish primary, secondary and tertiary amines is:

EASY
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Identify the Hinsberg’s reagent from the following.

MEDIUM
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The major product of the reaction is
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MEDIUM
IMPORTANT

Reactivity of benzene ring in the aniline can be decreased by treating it with